{"id":50,"date":"2017-11-22T12:56:07","date_gmt":"2017-11-22T12:56:07","guid":{"rendered":"http:\/\/www-bfc.mls.eng.osaka-u.ac.jp\/ItohLab\/?page_id=50"},"modified":"2024-11-22T14:03:26","modified_gmt":"2024-11-22T05:03:26","slug":"publication","status":"publish","type":"page","link":"http:\/\/www-bfc.mls.eng.osaka-u.ac.jp\/ItohLab\/?page_id=50","title":{"rendered":"Publication\/\u539f\u8457\u8ad6\u6587\u7b49"},"content":{"rendered":"\n

<\/p>\n\n\n

2024<\/em><\/p>\n

\n

Copper Complexes with Protein\u2010Based\u00a0N\u2010Donor Ligands as\u00a0cis\u2010Selective Nascent Cyclopropanases<\/strong>
Nobutaka Fujieda, Atsuki Matsuo, Shinobu Itoh
Chem. Eur. J., <\/em><\/i>2024<\/strong>, <\/em><\/i>e202402803 (1 of 5).
<\/strong>DOI: 10.1002\/chem.202402803<\/p>\n

Structure and substitution effects of iron complexes of dibenzotetraaza[14]annulene on oxygen reduction catalysis<\/strong>\u00a0
Masafumi Asahi, Shin-ichi Yamazaki, Shinobu Itoh, Tsutomu Ioroi
Inorg. Chim. Acta.<\/em>, <\/i>2024<\/strong>,<\/i> 572, 12991.
<\/strong>DOI: 10.1016\/j.ica.2024.122291<\/p>\n

Oxidation mechanism of phenols by copper(II)-halide complexes<\/strong>\u00a0
Lan Yang, Rin Ito, Hideki Sugimoto, Yuma Morimoto, Shinobu Itoh
Chem Commum., <\/i>2024<\/strong>, 60<\/i>, 7589-7589
<\/strong>DOI: 10.1039\/d4cc02483d<\/p>\n

Selective Alkane Hydroxylation in a Fluorous Solvent System Catalyzed by a Fluorocarbon-Soluble Transition-Metal Catalyst<\/strong>
Yuma Morimoto, Yuki Shimaoka, Kosuke Fukui, Shinobu Itoh
ACS Omega.,\u00a0<\/i>2024<\/strong>, 9, 22, 23624-23633.
<\/strong>DOI: 10.1021\/acsomega.4c01204<\/p>\n

A rhodium(II)\/rhoium(III) redox couple for C-H bond amination with alkylazides: a rhodium(III)-nitrenoid intermediate with a tetradentate [14]-macrocyclic ligand<\/strong>
Hideki Sugimoto, Megumu Sakaida, Yoshihito Shiota, Mayuko Miyanishi, Yuma Morimoto, Kazunari Yoshizawa, Shinobu Itoh
Dalton Trans.<\/i>, 2024<\/strong>, 53, 1607-1615.<\/em>
<\/strong>DOI: 10.1039\/d3dt03429a<\/p>\n

Asymmetric Michael addition catalysed by copper\u2013amyloid complexes<\/strong>
Nobutaka Fujieda, Atsushi Tonomura, Tomofumi Mochizuki, Shinobu Itoh
RSC Adv<\/em>., 2024<\/strong>, 14, 206-210.
<\/strong>DOI: 10.1039\/d3ra07900g<\/p>\n

2023<\/em><\/p>\n

\n

Mechanistic Studies on Oxygen-Insertion into Osmium(III)\u2013Carbon Bond via High-Valent Oxido-Osmium(V) Complex<\/strong>\u00a0
Hideki Sugimoto, Kurumi Aoki, Shinobu Itoh
Bull. Chem. Soc. Jpn<\/em>., 2023<\/strong>, 96<\/em> (11), 1310-1315.
<\/strong>DOI: 10.1246\/bcsj.20230213<\/p>\n

Mechanistic studies on catalytic alkane oxidation by Murahashi’s O2<\/sub>\/copper(ii<\/span>)\/aldehyde system
<\/strong>Kohei Yamaguchi, Yuya Uemura, Hideki Sugimoto, Rin Ito, Yuma Morimoto, Shinobu Itoh
Catal. Sci. Technol.,<\/i> 2023<\/strong>, 13, 5859-5867.
DOI: 10.1039\/d3cy00944k<\/p>\n

Characterization and Reactivity Studies of Mononuclear Tetrahedral Copper(II)\u2013Halide Complexes\u00a0
<\/strong>Yang Lan, Yuma Morimoto, Ikuma Shimizu, Hideki Sugimoto, Shinobu Itoh
Inorg. Chem<\/em>., 2023<\/strong>, 62, 27, 10539\u201310547.
DOI: 10.1021\/acs.inorgchem.3c00320<\/p>\n

Oxygenase mimicking immobilised iron complex catalysts for alkane hydroxylation with H2<\/sub>O2<\/sub>
<\/strong>Seiya Sakakura, Ryunosuke Kitamoto, Kazuki Goto, Seito Miura, Takamasa Takeda, Masaya Okamura, Arisa Fukatsu, Shinobu Itoh, Shiro Hikichi
Catal. Sci. Technol.<\/i>, 2023<\/strong>, 13, 4839-4846.
DOI: 10.1039\/D3CY00698K<\/p>\n

2022<\/em><\/p>\n

\n

Alkane hydroxylation by m-chloroperbenzoic acid catalyzed by nickel(II) complexes of linear N4-tetradentate ligands\u00a0<\/strong>
Takuma Wada, Hideki Sugimoto, Yuma Morimoto, Shinobu Itoh
Polyhedron. <\/em>2022<\/strong>, <\/em>227, 116150-116150.\u00a0<\/em>
<\/strong>DOI: 10.1016\/j.poly.2022.116150<\/p>\n

Dioxygen Activation and Mandelate Decarboxylation by Iron(II) Complexes of N4 Ligands: Evidence for Dioxygen-Derived Intermediates from Cobalt Analogues\u00a0<\/strong>
Rahul Dev Jana, Biswarup Chakraborty, Sayantan Paria, Takehiro Ohta, Reena Singh, Sourav Mandal, Satadal Paul, Shinobu Itoh, Tapan Kanti Paine
Inorg. Chem. <\/em>2022<\/strong>,<\/em> 61 (27), 10461-10476.
<\/strong>DOI: 10.1021\/acs.inorgchem.2c01308<\/p>\n

Alkane Oxidation with H2O2 Catalyzed by OsO4-carboxylate Adduct and Its Application to Heterogeneous Catalyst<\/strong>
Tomohiro Fujimoto, Yuta Ueda, Hideki Sugimoto, Jun Nakazawa, Shiro Hikichi, Shinobu Itoh
Chem. Lett. <\/em>2024<\/strong>, <\/em>51 (3), 231-234.
<\/strong>DOI: 10.1246\/cl.210751<\/p>\n

Halide-Adducts of OsO4<\/sub>. Structure and Reactivity in Alcohol-Oxidation <\/strong>
Tomohiro Fujimoto, Yuka Hirata, Hideki Sugimoto,* Mayuko Miyanishi, Yoshihito Shiota, Kazunari Yoshizawa,* and Shinobu Itoh*
Bull. Chem. Soc. Jpn<\/em>., 2022<\/strong>, 95<\/em> (1), 64-72. Selected Paper
<\/strong>DOI: 10.1246\/bcsj.20210377<\/p>\n

C(sp3<\/sup>)\u2013H bond activation by carboxylate-adduct of osmium tetroxide (OsO4<\/sub>)<\/strong>
Tomohiro Fujimoto, Yuka Hirata, Hideki Sugimoto,* Mayuko Miyanishi, Yoshihito Shiota, Kazunari Yoshizawa* and Shinobu Itoh*
<\/sup>Dalton <\/em>Trans<\/em>. 2022<\/strong>, 51<\/em> (3), 1123-1130.
DOI: 10.1039\/D1DT03819B<\/p>\n

2021
<\/em><\/p>\n

\n

Tin(II)-Nitrene Radical Complexes Formed by Electron Transfer from Redox-Active Ligand to Organic Azides and Their Reactivity in C(sp3)\u2013H Activation<\/strong>
Hideki Sugimoto,* Mayuka Yano, Kazunobu Sato,* Mayuko Miyanishi, Kenji Sugisaki, Yoshihito Shiota, Akira Kaga, Kazunari Yoshizawa,* and Shinobu Itoh*
Inorg. Chem<\/em>. 2021<\/strong>, 60 (24), 18603-18607. Inside Cover\u00a0<\/em><\/strong>
DOI: doi.org\/10.1021\/acs.inorgchem.1c02806<\/p>\n

Revisiting Alkane Hydroxylation with m<\/em>-CPBA (m<\/em>-Chloroperbenzoic Acid) Catalyzed by Nickel(II) Complexes<\/strong>
Tomoya Shinke, Mayu Itoh, Sachiko Yanagisawa, Yuma Morimoto, Hideki Sugimoto, Minoru Kubo, and Shinobu Itoh*
Chem. Eur. J.<\/em> 2021<\/strong>, 27<\/em> (59), 14730-14737.
DOI: 10.1002\/chem.202102532<\/p>\n

Controlling Reactivity of Copper(II) Acylperoxide Complexes<\/strong>
Yuma Morimoto, Makito Kawai, Aya Nakanishi, Hideki Sugimoto, and Shinobu Itoh*
Inorg. Chem.<\/em> 2021<\/strong>, 60, 8554-8565.\u00a0 Inside Cover\u00a0<\/em><\/strong>
DOI: 10.1021\/acs.inorgchem.1c00475<\/p>\n

Oxygen Atom Insertion into Osmium\u2013Carbon Bond via Organometallic Oxido-Osmium(V) Intermediate<\/strong>
Hideki Sugimoto,* Kurumi Aoki, Mayuko Miyanishi, Yoshihito Shiota, Kazunari Yoshizawa, Kazunari, and Shinobu Itoh*
Organometallics<\/em>, 2021<\/strong>, 40<\/em> (2), 102-106
DOI: 10.1021\/acs.organomet.0c00772<\/p>\n

Hydroxylation of Unactivated C(sp3)\u2013H Bonds with m-CPBA Catalyzed by FeIII-complex Supported by Trianionic Planar Tetradentate Ligand<\/strong>
Yuma Morimoto,* Shinichi Hanada, Ryusuke Kamada, Arisa Fukatsu, Shinsuke Okabe, Hideki Sugimoto, and Shinobu Itoh*
Inorg. Chem.<\/em> 2021<\/strong>, 60<\/em> (11), 7641-7649. Front Cover<\/strong><\/em>
DOI: 10.1021\/acs.inorgchem.0c03469<\/p>\n

Review in Japanese<\/em><\/span>
\u30c1\u30ed\u30b7\u30ca\u30fc\u30bc\u53cd\u5fdc\u6a5f\u69cb\u306b\u304a\u3051\u308b\u9285\u6d3b\u6027\u9178\u7d20\u7a2e\u306e\u52d5\u7684\u6319\u52d5<\/strong>
\u85e4\u679d\u4f38\u5b87\u3001\u4f0a\u6771\u3000\u5fcd
\u751f\u5316\u5b66, <\/em>2021<\/strong>, 93<\/em> (4), 521-525.
Journal of Japanese Biochemical Society<\/em> 93(4): 521-525 (2021)
DOI: 10.14952\/SEIKAGAKU.2021.930521<\/p>\n

Book Chapter
<\/em><\/span>8.10 – Dioxygen-Binding in Metalloproteins and Corresponding Models
<\/strong>Shinobu Itoh, Hiroshi Fujii\u00a0
in Constable, E.; Parkin, G.; Que, L., Jr. (Ed.), Comprehensive Coordination Chemistry III <\/em>(pp. 200-237). <\/em>Elsevier Science: 2021.
<\/em><\/p>\n

2020<\/em><\/p>\n

\n

Modelling a \u2018histidine brace\u2019 motif in mononuclear copper monooxygenases<\/strong>
Arisa Fukatsu; Yuma Morimoto; Hideki Sugimoto; Shinobu Itoh*
Chem. Commun<\/em>. 2020<\/strong>, 56<\/em>, 5123-5126.
DOI: 10.1039\/D0CC01392G
\"\"
Chosen as an inside cover\u00a0<\/em><\/p>\n

2019<\/em><\/p>\n

\n

Direct Observation of Primary C\u2013H Bond Oxidation by an Oxido-Iron(IV) Porphyrin \u03c0-Radical Cation Complex in a Fluorinated Carbon Solvent<\/strong>
Yuma Morimoto*; Yuki Shimaoka; Yuri Ishimizu; Hiroshi Fujii*; Shinobu Itoh*
Angew. Chem. Int. Ed.<\/em> 2019<\/strong>, 58<\/em>, 10863-10866.
DOI: 10.1002\/anie.201901608<\/p>\n

Characterization and Reactivity of a Tetrahedral Copper(II)-Alkylperoxido Complex<\/strong>
Ikuma Shimizu; Yuma Morimoto; Gunasekaran Velmurugan; Tulika Gupta; Sayantan Paria; Takehiro Ohta; Hideki Sugimoto; Takashi Ogura; Peter Comba*; Shinobu Itoh*
Chem.\u2013Eur. J.<\/em> 2019<\/strong>, 25<\/em>,\u00a011157-11165
DOI: 10.1002\/chem.201902669<\/p>\n

Oxido-Hydroxido- and Oxido-Aminato-Osmium(V) Complexes with a Cyclohexanediamine-Based Tetradentate Ligand as Active Oxidants for Dihydroxylation and Aminohydroxylation of Alkenes
<\/strong>Tomohiro Fujimoto; Hideki Sugimoto*; Kenichiro Kai; Kazuki Maeda; Shinobu Itoh*
Eur. J. Inorg. Chem.<\/em> 2019<\/strong>, 2891-2898.
DOI: 10.1002\/ejic.2019003390<\/p>\n

<\/p>\n

Oxido-alcoholato\/thiolato-molybdenum(VI) complexes with a dithiolene ligand generated by oxygen atom transfer to the molybdenum(IV) complexes.<\/strong>
Hideki Sugimoto;* Masanori Sato; Kaoru Asano; Takeyuki Suzuki; Takashi Ogura; Shinobu Itoh*
Inorg. Chim. Acta<\/em>, 2019<\/strong>, 485<\/em>, 42-48.
DOI: 10.1016\/j.ica.2018.10.001<\/p>\n

\"\"<\/p>\n

Cupric-superoxide complex that induces a catalytic aldol reaction-type C\u2013C bond formation
<\/strong>Tsukasa Abe; Yuta Hori; Yoshihito Shiota; Takehiro Ohta; Yuma Morimoto; Hideki Sugimoto; Takashi Ogura; Kazunari Yoshizawa*; Shinobu Itoh*
Commun. Chem<\/em>. 2019<\/strong>, 2<\/em>, Article number: 12
(DOI: 10.1038\/s42004-019-0115-6)<\/p>\n

Our first paper in 2019 is published from Communication of Chemistry, which is a new chemistry journal of Nature.com<\/a>.<\/p>\n

\"\"\u00a0\u00a0\"\"<\/p>\n

2018<\/em><\/p>\n

\n

Non-innocent Ligand in Rhodium(III) Complex Catalyzed C-H Bond Amination with Tosyl Azide<\/strong>
Daiki Fujita, Hideki Sugimoto*, Yuma Morimoto, Shinobu\u00a0Itoh*
Inorg. Chem<\/em>.\u00a02018<\/strong>, 57<\/em>, 9738\u20139747.
(DOI: 10.1021\/acs.inorgchem.8b00289)<\/p>\n

\"\"\"\"<\/p>\n

A Bis(\u00b5-oxido)dinickel(III) Complex with a Triplet Ground State<\/strong>
Yuma Morimoto*, Yusaku Takagi, Toru Saito, Takehiro Ohta, Takashi Ogura, Norimitsu Tohnai, Motohiro Nakano, Shinobu Itoh*
Angew. Chem., Int. Ed.<\/em> 2018<\/strong>, 57<\/em>,\u00a07640-7643.
(DOI: 10.1002\/anie.201802779)<\/p>\n

\"\"\"\"<\/p>\n

Copper(I)\u2013Dioxygen Reactivity in the Isolated Cavity of a\u00a0Nanoscale Molecular Architecture<\/strong>
Sayantan Paria, Yuma Morimoto, Takehiro Ohta, Shinsuke Okabe, Hideki Sugimoto, Takashi Ogura, Shinobu Itoh*
Eur. J. Inorg. Chem.<\/em> 2018<\/strong>, 1976-1983. \u00a0(DOI: 10.1002\/ejic.201800029)<\/p>\n

\"\"<\/p>\n

Tyrosinases in Organic Chemistry: A Versatile Tool for the \u03b1-Arylation of -Dicarbonyl Compounds<\/strong>
Roxanne Krug, Dennis Schr\u00f6der, Jan Gebauer, Sanel Sulji\u0107, Yuma Morimoto, Nobutaka Fujieda, Shinobu Itoh, and J\u00f6rg Pietruszka*
Eur. J. Org. Chem.<\/em> 2018<\/strong>, 1789\u20131796.
(DOI: 10.1002\/ejoc.201800188)<\/p>\n

\"\"<\/p>\n

\u00a0<\/strong><\/p>\n

Osmium Complexes Coordinated with Poly(pyridylmethyl)diamine Hexadantate Ligands<\/strong>
Hideki Sugimoto,* Kahori Kiriyama, and Shinobu Itoh*
Eur J. Inorg. Chem. 2018 (2), 178-185.
DOI: 10.1002\/ejic.201701173<\/p>\n

\"\"<\/p>\n

Crystal Structure and Oxygen Reduction Reaction (ORR) Activity of Copper(II) Complexes of Pyridylmethylamine Ligands Containing a Carboxy Group<\/strong>
Masafumi Asahi,* Shin-ichi Yamazaki, Yuma Morimoto, Shinobu Itoh, Tsutomu Ioroi
Inorg. Chim. Acta, 2018, 471, 91-98.
DOI: https:\/\/doi.org\/10.1016\/j.ica.2017.10.031.<\/p>\n

\"\"\u00a0\"\"<\/p>\n

2-(2-Pyridyl)ethylamine (Pye) ligands in copper(I)-dioxygen chemistry<\/strong>
Shinobu Itoh,* Tsukasa Abe, Yuma Morimoto, and Hideki Sugimoto
Inorg. Chim. Acta (Special issue of “Bio-inorganic and bio-inspired chemistry of copper”), 2018, 481, 38-46.
DOI: 10.1016\/j.ica.2017.09.017<\/p>\n

\u751f\u4f53\u6a21\u5023\u578b\u30aa\u30b9\u30df\u30a6\u30e0\u932f\u4f53\u3092\u89e6\u5a92\u3068\u3059\u308b\u30a2\u30eb\u30b1\u30f3\u306e\u9178\u5316\u7684\u5909\u63db\u53cd\u5fdc <\/strong>
\u6749\u672c\u79c0\u6a39 \u30fb \u4f0a\u6771 \u5fcd
\u6709\u6a5f\u5408\u6210\u5316\u5b66\u5354\u4f1a\u8a8c\uff08\u7dcf\u5408\u8ad6\u6587\uff09, 75 (9), 929-940 (2017). DOI: 10.5059\/yukigoseikyokaishi.75.929<\/p>\n

\u9285\u542b\u6709\u30e2\u30ce\u30aa\u30ad\u30b7\u30b2\u30ca\u30fc\u30bc\u306b\u3088\u308b\u9178\u7d20\u5206\u5b50\u306e\u6d3b\u6027\u5316\u6a5f\u69cb<\/strong>
\u4f0a\u6771\u3000\u5fcd\u3001\u85e4\u679d\u4f38\u5b87
\u751f\u5316\u5b66\u300190 (3), 320-327 (2018)
DOI: 10.14952\/SEIKAGAKU.2018.900320<\/p>\n

Structures, Functions, and Assembly of Tyrosinases and Hemocyanins<\/strong>
Nobutaka Fujieda and Shinobu Itoh <\/strong>
Encyclopedia of Inorganic and Bioinorganic Chemistry (ISBN 9781119159834),
edited by Robert A. Scott., John Wiley & Sons, Ltd: Chichester, UK, 2017.
DOI: 10.1002\/9781119951438.eibc2474 (SEPTEMBER 22, 2017).<\/p>\n

2017<\/em><\/p>\n

\n

Copper-Catalyzed Selective Oxygenation of Methyl and Benzyl Substituents in Pyridine with O2<\/strong>
Tsukasa Abe, Shinji Tanaka, Atsuko Ogawa, Masanori Tamura, Kazuhiko Sato,* and Shinobu Itoh*
Chem. Lett. 2017, 47 (3), 348-350.
DOI: http:\/\/dx.doi.org\/10.1246\/cl.161074. Publication Date (Web): March 29, 2017.<\/p>\n

\"\"\u00a0\"\"<\/p>\n


Dioxygenation of Flavonol Catalyzed by CuII-complexes Supported by Carboxylate-containing Ligands. Structural and Functional Models of Quercetin 2,4-Dioxygenase (2,4-QD)<\/strong>
Ying-Ji Sun,* Pei Li, Qian-Qian Huang, Jian-Jun Zhang, and Shinobu Itoh*
Eur. J. Inorg. Chem. 2017 (13), 1845-1854.
DOI: 10.1002\/ejic.201601371. Publication Date (Web): February 16, 2017.<\/p>\n

\"\"<\/p>\n

A Well-Defined Osmium-Cupin Complex: Hyperstable Artificial Osmium Peroxygenase<\/strong>
Nobutaka Fujieda,* Takumi Nakano, Yuki Taniguchi, Haruna Ichihashi, Hideki Sugimoto, Yuma Morimoto, Yousuke Nishikawa, Genji Kurisu, and Shinobu Itoh*
J. Am. Chem. Soc. 2017, 139 (14), 5149-5155.
DOI: 10.1021\/jacs.7b00675. Publication Date (Web): March 24, 2017.<\/p>\n

\"\"<\/p>\n

Generation and characterisation of a stable nickel(II)-aminoxyl radical complex<\/strong>
Arnaud Parrot, Yuma Morimoto, Sayantan Paria, Hideki Sugimoto, Nobutaka Fujieda and Shinobu Itoh*
Dalton Trans. 2017, 46 (25), 8013-8016.
DOI: 10.1039\/C7DT01789H. Publication Date (Web): June 16, 2017.<\/p>\n

\"\"<\/p>\n

Catalytic C\u2013H amination driven by intramolecular ligand-to-nitrene one-electron transfer through a rhodium(III) center<\/strong>
Daiki Fujita, Hideki Sugimoto,* Yoshihito Shiota, Yuma Morimoto, Kazunari Yoshizawa and Shinobu Itoh*
Chem. Comm. 2017, 53 (35), 4849-4852.
DOI: 10.1039\/C7CC01840A, Publication Date (Web): April 19, 2017.<\/p>\n

\"\"\u00a0\"\"<\/p>\n

Geometric Effects on O\u2013O Bond Scission of Copper(II)-alkylperoxide Complexes<\/strong>
Tsukasa Abe, Yuma Morimoto, Kaoru Mieda, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, and Shinobu Itoh*
J. Inorg. Biochem. 2017, 177, 375-383.
DOI: 10.1016\/j.jinorgbio.2017.08.016, Publication Date (Web): September 9, 2017.<\/p>\n

\"\"\u00a0 \u00a0\u00a0\"\"<\/p>\n

Tetrahedral Copper(II) Complexes with a Labile Coordination Site Supported by a tris-Tetramethylguanidinato Ligand<\/strong>
Ikuma Shimizu, Yuma Morimoto, Dieter Faltermeier, Marion Kerscher, Sayantan Paria, Tsukasa Abe, Hideki Sugimoto, Nobutaka Fujieda, Kaori Asano, Takeyuki Suzuki, Peter Comba,* and Shinobu Itoh*
Inorg. Chem. 2017, 2017, 56 (16), 9634-9645.
DOI: 10.1021\/acs.inorgchem.7b01154. Publication Date (Web): July 28, 2017.<\/p>\n

\"\"<\/p>\n

\u751f\u4f53\u6a21\u5023\u578b\u30aa\u30b9\u30df\u30a6\u30e0\u932f\u4f53\u3092\u89e6\u5a92\u3068\u3059\u308b\u30a2\u30eb\u30b1\u30f3\u306e\u9178\u5316\u7684\u5909\u63db\u53cd\u5fdc <\/strong>
\u6749\u672c\u79c0\u6a39 \u30fb \u4f0a\u6771 \u5fcd
\u6709\u6a5f\u5408\u6210\u5316\u5b66\u5354\u4f1a\u8a8c\uff08\u7dcf\u5408\u8ad6\u6587\uff09, 75 (9), 929-940 (2017).<\/p>\n

2-(2-Pyridyl)ethylamine (Pye) ligands in copper(I)-dioxygen chemistry<\/strong>
Shinobu Itoh,* Tsukasa Abe, Yuma Morimoto, and Hideki Sugimoto
Inorg. Chim. Acta (Special issue of “Bio-inorganic and bio-inspired chemistry of copper”), 2017, in press.
DOI: 10.1016\/j.ica.2017.09.017,<\/p>\n

\"\"\u00a0\u00a0\"\"<\/p>\n

\u7d9a \u5b9f\u9a13\u3092\u5b89\u5168\u306b\u884c\u3046\u305f\u3081\u306b\u2212\u57fa\u672c\u64cd\u4f5c\uff65\u57fa\u672c\u6e2c\u5b9a \u7de8\u2212<\/strong>\uff08\u7b2c\uff14\u7248\uff09
\u897f\u8107\u6c38\u654f\u30fb\u4f0a\u6771\u3000\u5fcd\u30fb\u5c0f\u5ee3\u548c\u54c9\u30fb\u5357\u65b9\u8056\u53f8
\u5316\u5b66\u540c\u4eba\u30012017\u5e742\u670810\u65e5
ISBN 978-4-7598-1834-5<\/p>\n

\"\"<\/p>\n

Structures, Functions, and Assembly of Tyrosinases and Hemocyanins<\/strong>
Nobutaka Fujieda and Shinobu Itoh
Encyclopedia of Inorganic and Bioinorganic Chemistry (ISBN 9781119159834),
edited by Robert A. Scott., John Wiley & Sons, Ltd: Chichester, UK, 2017.
DOI: 10.1002\/9781119951438.eibc2474 (SEPTEMBER 22, 2017).<\/p>\n

2016<\/em><\/p>\n

\n

Acid-base and redox equilibria of a tris(2-pyridylmethyl)amine copper complex; their effects on electrocatalytic oxygen reduction by the complex.<\/strong>
Masafumi Asahi, Shin-ichi Yamazaki, Shinobu Itoh, Tsutomu Ioroi
Electrochimica Acta, in press (2016).<\/p>\n

Oxidative Cyclization of 1,5-Dienes with Hydrogen Peroxide Catalyzed by an Osmium(III) Complex: Synthesis of cis- Tetrahydrofurans<\/strong>
Hideki Sugimoto, Takayuki Kanetake, Kazuki Maeda, and Shinobu Itoh
Org. Lett. 18 (6), 1246\u20131249 (2016).<\/p>\n

\"\"<\/p>\n

Cerium-Complex-Catalyzed Oxidation of Arylmethanols under Atmospheric Pressure of Dioxygen and Its Mechanism through a Side-On \u03bc-Peroxo Dicerium(IV) Complex.<\/strong>
Mitali Paul, Satoru Shirase, Yuma Morimoto, Laurent Mathey, Balasubramanian Murugesapandian, Shinji Tanaka, Shinobu Itoh, Hayato Tsurugi,* and Kazushi Mashima*
Chem. Eur. J. 22 (12), 4008 \u2013 4014 (2016).<\/p>\n

\"\"<\/p>\n

A Model for the Active-Site Formation Process in DMSO Reductase Family Molybdenum Enzymes Involving Oxido\u2212Alcoholato and Oxido\u2212Thiolato Molybdenum(VI) Core Structures <\/strong>
Hideki Sugimoto,* Masanori Sato, Kaori Asano, Takeyuki Suzuki, Kaoru Mieda, Takashi Ogura, Takashi Matsumoto, Logan J. Giles, Amrit Pokhrel, Martin L. Kirk,* and Shinobu Itoh*
Inorg. Chem. 55 (4), 1542-1550 (2016).<\/p>\n

\"\"<\/p>\n

Controlling Dicopper Protein Functions<\/strong>
Nobutaka Fujieda and Shinobu Itoh*
Bull. Chem. Soc. Jpn. 2016, 89 (7), 733-742 (2016)
Award Accounts (CSJ Award for Creative Work in 2014).
DOI: 10.1246\/bcsj.20150444<\/p>\n

\"\"\u00a0 \u00a0\u00a0\"\"<\/p>\n

\u30d5\u30ed\u30f3\u30c6\u30a3\u30a2\u751f\u7269\u7121\u6a5f\u5316\u5b66\u3000<\/strong>\u932f\u4f53\u5316\u5b66\u4f1a\u30d5\u30ed\u30f3\u30c6\u30a3\u30a2\u9078\u66f8
\u4f0a\u6771\u3000\u5fcd\u3001\u9752\u91ce\u91cd\u5229\u3001\u6797\u3000\u9ad8\u53f2\u3000\u7de8\u8457
\u4e09\u5171\u51fa\u7248\u30012016\u5e7412\u67081\u65e5
ISBN: 978-4-7827-0756-2<\/p>\n

\"\"<\/p>\n

2015<\/em><\/p>\n

\n

Generation, Characterization, and Reactivity of a CuII\u2212Alkylperoxide\/Anilino Radical Complex: Insight into the O\u2212O Bond Cleavage Mechanism<\/strong>
Sayantan Paria, Takehiro Ohta, Yuma Morimoto, Takashi Ogura, Hideki Sugimoto, Nobutaka Fujieda, Kei Goto, Kaori Asano, Takeyuki Suzuki, and Shinobu Itoh*
J. Am. Chem. Soc. 137 (34), 10870\u201310873 (2015).<\/p>\n

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cis-1,2-Aminohydroxylation of Alkenes Involving a Catalytic Cycle of Osmium(III) and Osmium(V) Centers: OsV(O)(NHTs) Active Oxidant with a Macrocyclic Tetradentate Ligand
<\/strong>Hideki Sugimoto,* Akine Mikami, Kenichiro Kai, P. K. Sajith, Yoshihito Shiota, Kazunari Yoshizawa,* Kaori Asano, Takeyuki Suzuki, and Shinobu Itoh*
Inorg. Chem. 54 (14), 7073-7082 (2015). 10.1021\/acs.inorgchem.5b01083 (June 30, 2015).<\/p>\n

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Developing Mononuclear Copper Active-oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions
<\/strong>Shinobu Itoh
Acc. Chem. Res. 48 (7), 2066-2074 (2015).\u00a0 10.1021\/acs.accounts.5b00140 (June 18, 2015).<\/p>\n

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Direct Hydroxylation of Benzene to Phenol Using Hydrogen Peroxide Catalyzed by Nickel Complexes Supported by Pyridylalkylamine Ligands<\/strong>
Yuma Morimoto, Shuji Bunno, Nobutaka Fujieda, Hideki Sugimoto, and Shinobu Itoh*
J. Am. Chem. Soc. 137 (18), 5867-5870 (2015). 10.1021\/jacs.5b01814 (May 4, 2015).<\/p>\n

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Solubilisation of a 2,2-diphenyl-1-picrylhydrazyl radical in water by \u03b2-cyclodextrin to evaluate the radical-scavenging activity of antioxidants in aqueous media<\/strong>
Ikuo Nakanishi, Kei Ohkubo, Kohei Imai, Masato Kamibayashi, Yasuo Yoshihashi, Ken-ichiro Matsumoto, Kiyoshi Fukuhara, Katsuhide Terada, Shinobu Itoh, Toshihiko Ozawa and Shunichi Fukuzumi
Chem. Commun. 51, 8311-8314 (2015).\u00a0\u00a010.1039\/C5CC02236C (April 4, 2015)<\/p>\n

\"\"<\/p>\n

Fungal Pro-tyrosinase<\/strong>
Nobutaka Fujieda and Shinobu Itoh
Handbook of Metalloproteins to the Encyclopedia of Inorganic and Bioinorganic Chemistry
<\/span>Robert Huber, Thomas Poulos, and Karl Wieghardt, Eds, John Wiley & Sons, UK, 2015, in press.<\/span><\/p>\n

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\u03b2-Diketiminates as Redox Non-innocent Supporting Ligands in Coordination Chemistry<\/strong>
Shinobu Itoh and Yuma Morimoto
Chemical Science of \u03c0-Electron Systems, Akasaka, T.; Osuka, A.; Fukuzumi, S.; Kandori, H.; Aso, Y. Eds., Springer, Tokyo, 2015, pp 715-730.<\/p>\n

Redox behavior of novel nickel and palladium complexes supported by trianionic non-innocent ligand containing \u03b2-diketiminate and phenol groups<\/strong>
Yuma Morimoto, June Takaichi, Shinichi Hanada, Kei Ohkubo, Hideki Sugimoto, Nobutaka Fujieda, Shunichi Fukuzumi and Shinobu Itoh*
J. Porphyrins Phthalocyanines 19, 377\u2013387 (2015). 10.1142\/S1088424615500248<\/p>\n

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\u9244\u3068\u9178\u7d20\u304c\u51fa\u4f1a\u3063\u305f\u77ac\u9593\u3092\u6349\u3048\u308b\u301c\u3088\u3046\u3084\u304f\u59ff\u3092\u73fe\u3057\u305f\u30b9\u30fc\u30da\u30eb\u30aa\u30ad\u30b7\u30c9\u9244\u932f\u4f53<\/strong>
\u68ee\u672c\u7950\u9ebb\uff65\u4f0a\u6771\u3000\u5fcd
\u6708\u520a\u300c\u5316\u5b66\u300d\uff08\u6700\u65b0\u306e\u30c8\u30d4\u30c3\u30af\u30b9\uff09, 70 (9), 64\u201365 (2015).<\/p>\n

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\u30d6\u30eb\u30fc\u30b9\u6709\u6a5f\u5316\u5b66\uff08\u7b2c7\u7248\uff09
<\/strong>Paula Y. Bruice\u8457\u3001\u5927\u8239\u6cf0\u53f2\u3089\uff08\u76e3\u4fee\uff09
\u4f0a\u6771\u3000\u5fcd\u3089\uff08\u8a33\uff09
\u5316\u5b66\u540c\u4eba\u3001pp 1235-1313\uff08\u7b2c23\uff0c24\u7ae0\uff09\uff082015\uff09<\/p>\n

\"\"<\/p>\n

2014<\/em><\/p>\n

\n

A Tetradentate \u03b2-Diiminato Ligand Containing Phenolate Substituents: Flexivalent Coordination to Mn(III), Co(III), Ni(II), and Cu(II)<\/strong>
Fadhil Lafta Faraj, Hamid Khaledi,* Yuma Morimoto, Shinobu Itoh, Marilyn M. Olmstead, and Hapipah Mohd Ali
Eur. J. Inorg. Chem. 2014, 5752-5759.<\/p>\n

Geometric Control of Nuclearity in Copper(I)\/Dioxygen Chemistry<\/strong>
Tsukasa Abe, Yuma Morimoto, Tetsuro Tano, Kaoru Mieda, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, and Shinobu Itoh*
Inorg. Chem. 53 (16), 8786-8794 (2014). 10.1021\/ic501461n<\/p>\n

Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: relationship between activity and redox potential<\/strong>
Masafumi Asahi,* Shin-ichi Yamazaki, Shinobu Itoh, and Tsutomu Ioroi
Dalton Trans. 43 (28), 10705-10709 (2014). 10.1039\/C4DT00606B<\/p>\n

Redox Chemistry of Nickel(II)-Complexes Supported by a Series of Non-innocent \u03b2-Diketiminate Ligands<\/strong>
June Takaichi, Yuma Morimoto, Kei Ohkubo, Chizu Shimokawa, Takayuki Hojo, Seiji Mori,* Haruyasu Asahara, Hideki Sugimoto, Nobutaka Fujieda, Nagatoshi Nishiwaki, Shunichi Fukuzumi, and Shinobu Itoh*
Inorg. Chem. 53 (12), 6159-6169 (2014). 10.1021\/ic5006693<\/p>\n

Copper complexes supported by an N2S-tridentate ligand as active site models of copper monooxygenases<\/strong>
Tetsuro Tano, Hideki Sugimoto and Shinobu Itoh*
Dalton Trans. 43 (12), 4871-4877 (2014). 10.1039\/C3DT52952E<\/p>\n

2013<\/em><\/p>\n

\n

Redox Properties of Mononuclear Copper(II)-Superoxide Complex<\/strong>
Tetsuro Tano, Yuri Okubo, Atsushi Kunishita, Minoru Kubo, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, and Shinobu Itoh*
Inorg. Chem. 52 (18), 10431-10437 (2013).<\/p>\n

Flavonolate Complexes of MII (M = Mn, Fe, Co, Ni, Cu, and Zn). Structural and Functional Models for the ES (Enzyme-Substrate) Complex of Quercetin 2,3-Dioxygenase<\/strong>
Ying-Ji Sun,* Qian-Qian Huang, Tetsuro Tano, and Shinobu Itoh
Inorg. Chem. 52 (19), 10936-10948 (2013).<\/p>\n

Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligand related to the active site of type II class of DMSOR family of molybdoenzymes<\/strong>
Hideki Sugimoto,* Masanori Sato, Logan J. Giles, Kaori Asano, Takeyuki Suzuki, Martin L. Kirk,* and Shinobu Itoh*
Dalton Trans. in press (2013).<\/p>\n

Crystal Structures Of Copper-Depleted And Copper-Bound Fungal Pro-Tyrosinase: Insights Into Endogenous Cysteine-Dependent Copper Incorporation<\/strong>
Nobutaka Fujieda, Shintaro Yabuta, Takuya Ikeda, Takuji Oyama, Norifumi Muraki, Genji Kurisu,* and Shinobu Itoh*
J. Biol. Chem. 288 (30), 22128-22140 (2013).<\/p>\n

Osmium(III) and Osmium(V) Complexes Bearing a Macrocyclic Ligand: A Simple and Efficient Catalytic System for cis-Dihydroxylation of Alkenes with Hydrogen Peroxide<\/strong>
Hideki Sugimoto,* Kenji Ashikari, and Shinobu Itoh*
Chem. Asian J. 8 (9), 2154-2160 (2013).<\/p>\n

C\u2013H Bond Activation of the Methyl Group of Supporting Ligand in an Osmium(III) Complex upon the Reaction with H2O2: Formation of an Organometallic Osmium(IV) Complex<\/strong>
Hideki Sugimoto,* Kenji Ashikari, and Shinobu Itoh*
Inorg. Chem. 52 (2), 543-545 (2013).<\/p>\n

Copper complexes of non-innocent \u03b2-diketiminate ligand containing phenol groups<\/strong>
June Takaichi, Kei Ohkubo, Hideki Sugimoto, Motohiro Nakano, Daisuke Usa, Hiroaki Maekawa, Nobutaka Fujieda, Nagatoshi Nishiwaki, Shu Seki, Shunichi Fukuzumi, and Shinobu Itoh*
Dalton Trans. 41 (7), 2438-2444 (2013).<\/p>\n

A new series of bis(ene-1,2-dithiolato)tungsten(IV), -(V), -(VI) complexes as reaction centre models of tungsten enzymes: preparation, crystal structures and spectroscopic properties.<\/strong>
Hideki Sugimoto,* Kohei Hatakeda, Kazuo Toyota, Susumu Tatemoto, Minorun Kubo, Takashi Ogura and Shinobu Itoh*
Dalton Trans. 41 (9), 3059-3070 (2013).<\/p>\n

Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: Low temperature preparation and characterisation<\/strong>
Hideki Sugimoto,* Susumu Tatemoto, Kazuo Toyota, Minoru Kubo, and Shinobu Itoh*
Chem. Commun. 49 (39), 4358-4360 (2013).<\/p>\n

Activation Mechanism of MelB Tyrosinase from Aspergillus oryzae by Acidic Treatment<\/strong>
Nobutaka Fujieda,* Michiaki Murata, Shintaro Yabuta, Takuya Ikeda, Chizu Shimokawa, Yukihiro Nakamura, Yoji Hata, Shinobu Itoh*
J. Biol. Inorg. Chem. 18 (1), 19-26 (2013).<\/p>\n

Before 2012<\/em><\/a><\/strong><\/p>\n\n\n

<\/p>\n","protected":false},"excerpt":{"rendered":"

2024 Copper Complexes with Protein\u2010Based\u00a0N\u2010Donor Ligands as\u00a0cis\u2010Selective Nascent Cyclopropanases Nobutaka Fujieda, Atsuki Matsuo, Shinobu ItohChem. Eur. J., 2024, e202402803 (1 of 5).DOI: 10.1002\/chem.202402803 Structure and substitution effects of iron complexes of dibenzotetraaza[14]annulene on oxygen reduction catalysis\u00a0Masafumi Asahi, Shin-ichi Yamazaki, Shinobu Itoh, Tsutomu IoroiInorg. Chim. Acta., 2024, 572, 12991.DOI: 10.1016\/j.ica.2024.122291 Oxidation mechanism of phenols by copper(II)-halide … <\/p>\n

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