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Last Updated on 2016. 12. 13.


論文・総説・著書・解説

2008年以降)


2016


錯体化学会フロンティア選書「フロンティア生物無機化学」
伊東 忍、青野重利、林 高史 編著
三共出版、2016121
ISBN: 978-4-7827-0756-2




Controlling Dicopper Protein Functions

Nobutaka Fujieda and Shinobu Itoh*
Bull. Chem. Soc. Jpn. 89 (7), 733-742 (2016) Award Accounts (CSJ Award for Creative Work in 2014). 10.1246/bcsj.20150444



Acid-base and redox equilibria of a tris(2-pyridylmethyl)amine copper complex; their effects on electrocatalytic oxygen reduction by the complex.
Masafumi Asahi, Shin-ichi Yamazaki, Shinobu Itoh, Tsutomu Ioroi

Electrochimica Acta, in press (2016).


Oxidative Cyclization of 1,5-Dienes with Hydrogen Peroxide Catalyzed by an Osmium(III) Complex: Synthesis of cis- Tetrahydrofurans
Hideki Sugimoto, Takayuki Kanetake, Kazuki Maeda, and Shinobu Itoh
Org. Lett. 18 (6), 1246–1249 (2016).


Cerium-Complex-Catalyzed Oxidation of Arylmethanols under Atmospheric Pressure of Dioxygen and Its Mechanism through a Side-On μ-Peroxo Dicerium(IV) Complex.

Mitali Paul, Satoru Shirase, Yuma Morimoto, Laurent Mathey, Balasubramanian Murugesapandian, Shinji Tanaka, Shinobu Itoh, Hayato Tsurugi,* and Kazushi Mashima*
Chem. Eur. J. 22 (12), 4008 – 4014 (2016).


A Model for the Active-Site Formation Process in DMSO Reductase Family Molybdenum Enzymes Involving Oxido−Alcoholato and Oxido−Thiolato Molybdenum(VI) Core Structures
Hideki Sugimoto,* Masanori Sato, Kaori Asano, Takeyuki Suzuki, Kaoru Mieda, Takashi Ogura, Takashi Matsumoto, Logan J. Giles, Amrit Pokhrel, Martin L. Kirk,* and Shinobu Itoh*
Inorg. Chem. 55 (4), 1542-1550 (2016).



2015


Generation, Characterization, and Reactivity of a CuII−Alkylperoxide/Anilino Radical Complex: Insight into the O−O Bond Cleavage Mechanism
Sayantan Paria, Takehiro Ohta, Yuma Morimoto, Takashi Ogura, Hideki Sugimoto, Nobutaka Fujieda, Kei Goto, Kaori Asano, Takeyuki Suzuki, and Shinobu Itoh*
J. Am. Chem. Soc. 137 (34), 10870–10873 (2015).


cis-1,2-Aminohydroxylation of Alkenes Involving a Catalytic Cycle of Osmium(III) and Osmium(V) Centers: OsV(O)(NHTs) Active Oxidant with a Macrocyclic Tetradentate Ligand

Hideki Sugimoto,* Akine Mikami, Kenichiro Kai, P. K. Sajith, Yoshihito Shiota, Kazunari Yoshizawa,* Kaori Asano, Takeyuki Suzuki, and Shinobu Itoh*

Inorg. Chem. 54 (14), 7073-7082 (2015). 10.1021/acs.inorgchem.5b01083 (June 30, 2015).


Developing Mononuclear Copper Active-oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions

Shinobu Itoh

Acc. Chem. Res. 48 (7), 2066-2074 (2015).  10.1021/acs.accounts.5b00140 (June 18, 2015).


Direct Hydroxylation of Benzene to Phenol Using Hydrogen Peroxide Catalyzed by Nickel Complexes Supported by Pyridylalkylamine Ligands
Yuma Morimoto, Shuji Bunno, Nobutaka Fujieda, Hideki Sugimoto, and Shinobu Itoh*
J. Am. Chem. Soc. 137 (18), 5867-5870 (2015). 10.1021/jacs.5b01814 (May 4, 2015).


Solubilisation of a 2,2-diphenyl-1-picrylhydrazyl radical in water by β-cyclodextrin to evaluate the radical-scavenging activity of antioxidants in aqueous media
Ikuo Nakanishi, Kei Ohkubo, Kohei Imai, Masato Kamibayashi, Yasuo Yoshihashi, Ken-ichiro Matsumoto, Kiyoshi Fukuhara, Katsuhide Terada, Shinobu Itoh, Toshihiko Ozawa and Shunichi Fukuzumi
Chem. Commun. 51, 8311-8314 (2015).  10.1039/C5CC02236C (April 4, 2015)


Fungal Pro-tyrosinase

Nobutaka Fujieda and Shinobu Itoh

Handbook of Metalloproteins to the Encyclopedia of Inorganic and Bioinorganic Chemistry,

Robert Huber, Thomas Poulos, and Karl Wieghardt, Eds, John Wiley & Sons, UK, 2015, in press.

β-Diketiminates as Redox Non-innocent Supporting Ligands in Coordination Chemistry
Shinobu Itoh and Yuma Morimoto

Chemical Science of π-Electron Systems, Akasaka, T.; Osuka, A.; Fukuzumi, S.; Kandori, H.; Aso, Y. Eds., Springer, Tokyo, 2015, pp 715-730.

Redox behavior of novel nickel and palladium complexes supported by trianionic non-innocent ligand containing β-diketiminate and phenol groups
Yuma Morimoto, June Takaichi, Shinichi Hanada, Kei Ohkubo, Hideki Sugimoto, Nobutaka Fujieda, Shunichi Fukuzumi and Shinobu Itoh*
J. Porphyrins Phthalocyanines 19, 377–387 (2015). 10.1142/S1088424615500248

鉄と酸素が出会った瞬間を捉える〜ようやく姿を現したスーペルオキシド鉄錯体
森本祐麻・伊東 忍
月刊「化学」(最新のトピックス), 70 (9), 64–65 (2015).


ブルース有機化学(第7版)Paula Y. Bruice著、大船泰史ら(監修)

伊東 忍ら(訳)

化学同人、pp 1235-1313(第2324章)(2015



2014


A Tetradentate β-Diiminato Ligand Containing Phenolate Substituents: Flexivalent Coordination to Mn(III), Co(III), Ni(II), and Cu(II)

Fadhil Lafta Faraj, Hamid Khaledi,* Yuma Morimoto, Shinobu Itoh, Marilyn M. Olmstead, and Hapipah Mohd Ali

Eur. J. Inorg. Chem. 2014, 5752-5759.


Geometric Control of Nuclearity in Copper(I)/Dioxygen Chemistry
Tsukasa Abe,
Yuma Morimoto, Tetsuro Tano, Kaoru Mieda, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, and Shinobu Itoh*
Inorg. Chem. 53 (16), 8786-8794 (2014). 10.1021/ic501461n


Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: relationship between activity and redox potential
Masafumi Asahi,* Shin-ichi Yamazaki, Shinobu Itoh, and Tsutomu Ioroi
Dalton Trans. 43 (28), 10705-10709 (2014). 10.1039/C4DT00606B


Redox Chemistry of Nickel(II)-Complexes Supported by a Series of Non-innocent β-Diketiminate Ligands
June Takaichi, Yuma Morimoto, Kei Ohkubo, Chizu Shimokawa, Takayuki Hojo, Seiji Mori,* Haruyasu Asahara, Hideki Sugimoto, Nobutaka Fujieda, Nagatoshi Nishiwaki, Shunichi Fukuzumi, and Shinobu Itoh*
Inorg. Chem. 53 (12), 6159-6169 (2014). 10.1021/ic5006693


Copper complexes supported by an N2S-tridentate ligand as active site models of copper monooxygenases
Tetsuro Tano, Hideki Sugimoto and Shinobu Itoh*
Dalton Trans. 43 (12), 4871-4877 (2014). 10.1039/C3DT52952E


2013


Redox Properties of Mononuclear Copper(II)-Superoxide Complex
Tetsuro Tano, Yuri Okubo,
Atsushi Kunishita, Minoru Kubo, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, and Shinobu Itoh*
Inorg. Chem. 52 (18), 10431-10437 (2013).

Flavonolate Complexes of MII (M = Mn, Fe, Co, Ni, Cu, and Zn). Structural and Functional Models for the ES (Enzyme-Substrate) Complex of Quercetin 2,3-Dioxygenase
Ying-Ji Sun,* Qian-Qian Huang, Tetsuro Tano, and Shinobu Itoh
Inorg. Chem. 52 (19), 10936-10948 (2013).


Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligand related to the active site of type II class of DMSOR family of molybdoenzymes
Hideki Sugimoto,* Masanori Sato, Logan J. Giles, Kaori Asano, Takeyuki Suzuki, Martin L. Kirk,* and Shinobu Itoh*
Dalton Trans. in press (2013).


Crystal Structures Of Copper-Depleted And Copper-Bound Fungal Pro-Tyrosinase: Insights Into Endogenous Cysteine-Dependent Copper Incorporation
Nobutaka Fujieda, Shintaro Yabuta, Takuya Ikeda, Takuji Oyama, Norifumi Muraki, Genji Kurisu,* and Shinobu Itoh*
J. Biol. Chem. 288 (30), 22128-22140 (2013).


Osmium(III) and Osmium(V) Complexes Bearing a Macrocyclic Ligand: A Simple and Efficient Catalytic System for cis-Dihydroxylation of Alkenes with Hydrogen Peroxide
Hideki Sugimoto,* Kenji Ashikari, and Shinobu Itoh*
Chem. Asian J. 8 (9), 2154-2160 (2013).




C–H Bond Activation of the Methyl Group of Supporting Ligand in an Osmium(III) Complex upon the Reaction with H2O2: Formation of an Organometallic Osmium(IV) Complex

Hideki Sugimoto,* Kenji Ashikari, and Shinobu Itoh*

Inorg. Chem. 52 (2), 543-545 (2013).


Copper complexes of non-innocent β-diketiminate ligand containing phenol groups

June Takaichi, Kei Ohkubo, Hideki Sugimoto, Motohiro Nakano, Daisuke Usa, Hiroaki Maekawa, Nobutaka Fujieda, Nagatoshi Nishiwaki, Shu Seki, Shunichi Fukuzumi, and Shinobu Itoh*

Dalton Trans. 41 (7), 2438-2444 (2013).


A new series of bis(ene-1,2-dithiolato)tungsten(IV), -(V), -(VI) complexes as reaction centre models of tungsten enzymes: preparation, crystal structures and spectroscopic properties.

Hideki Sugimoto,* Kohei Hatakeda, Kazuo Toyota, Susumu Tatemoto, Minorun Kubo, Takashi Ogura and Shinobu Itoh*

Dalton Trans. 41 (9), 3059-3070 (2013).




Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: Low temperature preparation and characterisation
Hideki Sugimoto,* Susumu Tatemoto, Kazuo Toyota, Minoru Kubo, and Shinobu Itoh*
Chem. Commun. 49 (39), 4358-4360 (2013).




Activation Mechanism of MelB Tyrosinase from Aspergillus oryzae by Acidic Treatment
Nobutaka Fujieda,* Michiaki Murata, Shintaro Yabuta, Takuya Ikeda, Chizu Shimokawa, Yukihiro Nakamura, Yoji Hata, Shinobu Itoh*
J. Biol. Inorg. Chem. 18 (1), 19-26 (2013).



2012


An Osmium(III)/Osmium(V) Redox Couple Generating OsV(O)(OH) Center for cis-1,2-Dihydroxylation of Alkenes with H2O2: Os Complex with a Nitrogen- based Tetradentate Ligand
Hideki Sugimoto,* Kazuhiro Kitayama, Seiji Mori, and Shinobu Itoh*
J. Am. Chem. Soc. 134 (46), 19270-19280 (2012).


Active Site Models for the CuB Site of PHM and DβH
Atsushi Kunishita,
Mehmed Z. Ertem, Yuri Okubo, Tetsuro Tano, Hideki Sugimoto, Kei Ohkubo, Nobutaka Fujieda, Shuichi Fukuzumi, Christopher J. Cramer,* and Shinobu Itoh

Inorg. Chem. 51 (17), 9465-9480 (2012).


Heterolytic Alkylhydroperoxide O–O Bond Cleavage by Copper(I) Complexes
Tetsuro Tano, Hideki Sugimoto, Nobutaka Fujieda, and Shinobu Itoh*
Eur. J. Inorg. Chem. 2012 (26), 4099–4103 (2012).


Copper(I)-Dioxygen Reactivity in a Sterically Demanding Tripodal Tetradentate tren Ligand. Formation and Reactivity of a Mononuclear Copper(II) End-on Superoxo Complex
Yuki Kobayashi, Kei Okubo, Takashi Nomura, Minoru Kubo, Nobutaka Fujieda, Hideki Sugimoto, Shunichi Fukuzumi, Kei Goto, Takashi Ogura, and Shinobu Itoh*
Eur. J. Inorg. Chem. 2012 (29), 4574-4578. [Cover Picture]




Artificial Dicopper Oxidase: Rational Reprogramming of Bacterial Metallo-β-lactamase into a Catechol Oxidase
Nobutaka Fujieda,*; Atsushi Hasegawa, Kenichi Ishihama, and Shinobu Itoh*
Chem. Asian J. 2012, 7 (6), 1203–1207. [Special Issue of 150 years of German–Japanese friendship]


Multifunctions of MelB, a Fungal Tyrosinase from Aspergillus oryzae

Nobutaka Fujieda,* Michiaki Murata, Shintaro Yabuta, Takuya Ikeda, Chizu Shimokawa,

Yukihiro Nakamura, Yoji Hata, and Shinobu Itoh*

ChemBioChem. 13 (2), 193–201 (2012).


2011


Copper-Oxygen Chemistry

Kenneth D. Karlin and Shinobu Itoh, Eds

John Wiley & Sons, Inc., Hoboken, New Jersey, 2011.




Chapter 8. Chemical Reactivity of Copper-Active Oxygen Complexes

Shinobu Itoh


Synthesis and Properties of Oxo-carboxylato- and Dioxo-bridged Diosmium Complexes of Tris(2- pyridylmethyl)amine
Hideki Sugimoto,* Kazuhiro Kitayama Kenji Ashikari, Chikako Matsunami, Naomi Ueda, Keisuke Umakoshi, Yuko Hosokoshi, Yoichi Sasaki,* and Shinobu Itoh*
Inorg. Chem. (Full Paper), 50 (18), 9014-9023 (2011).


Redox Reaction of Bis(dithiolene)sulfidotungsten(IV) Complex with Elemental Sulfur: Functional Analogues of Polysulfide Reductase of Molybdoenzymes.
Hideki Sugimoto,* Reiko Tajima, Kazuo Toyota, Hiroyuki Miyake, and Shinobu Itoh*
Chem. Lett. (Letter) 40 (10), 1146-1148 (2011). Editor’s Choice

Reactivity of copper(II)-alkylperoxo complexes.
Tetsuro Tano, Mehmed Z. Ertem, Satoru Yamaguchi, Atsushi Kunishita, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura,  Christopher J. Cramer,* and Shinobu Itoh*

Dalton Trans. (Full Paper), 40 (40), 10326-10336 (2011). Front Cover & Hot Article



Post-translational His-Cys Cross Linkage Formation in Tyrosinase Induced by Copper(II)-Peroxo Species.
Nobutaka Fujieda, Takuya Ikeda, Michiaki Murata, Sachiko Yanagisawa, Shigetoshi Aono, Kei Ohkubo, Satoshi Nagao, Takashi Ogura, Shun Hirota, Shunichi Fukuzumi, Yukihiro Nakamura, Yoji Hata, and Shinobu Itoh*

J. Am. Chem. Soc. (Communication), 133 (5), 1180–1183 (2011).


Reactions of Copper(II)-Phenol Systems with O2. Models Reaction for TPQ -Biosynthesis in in Copper Amine Oxidases.
Kae Tabuchi, Mehmed Z. Ertem,  Hideki Sugimoto, Atsushi Kunishita, Tetsuro Tano, Nobutaka Fujieda, Mehmed Z. Ertem, Christopher J. Cramer,* and Shinobu Itoh*
Inorg. Chem. (Article), 50 (5), 1633–1647 (2011).


Generation of bis(dithiolene)dioxomolybdenum(VI) complexes from bis(dithiolene)monooxomolybdenum(IV) complexes by proton-coupled electron transfer in aqueous media
Hideki Sugimoto,* Hiroyuki Tano, Hiroyuki Miyake, and Shinobu Itoh*
Dalton Trans. (Full Paper), 40 (10), 2358–2365 (2011).


Chalcogenidobis(ene–1,2–dithiolate)molybdenum(IV) complexes (chalcogenide E = S, Se): Probing Mo≡E and ene–1,2–dithiolate substituent effects on geometric and electronic structure.
Hideki Sugimoto,* Hiroyuki Tano, Koichiro Suyama, Tomoya, Kobayashi, Hiroyuki Miyake, Shinobu Itoh,* Regina P. Mtei, and Martin L. Kirk*
Dalton Trans. (Full Paper), 40 (5), 1119–1131 (2011).


Synthesis and Magnetic Properties of Dimethylmethylenebis(iminonitroxide) Diradical
Shuichi Suzuki, Noriaki Itoh, Kimiaki Furuichi, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Hiromi Ohi, Shinobu Itoh, and Keiji Okada*
Chem. Lett. (Communication), 40 (1), 22–24 (2011).


2010


Five monomeric hemocyanin subunits from Portunus trituberculatus: Purification, spectroscopic characterization, and quantitative evaluation of phenol monooxygenase activity.
Nobutaka Fujieda, Aki Yakiyama, and Shinobu Itoh*
Biochem. Biophys. Acta (Full Paper), 1804, 2128-2135 (2010).


Resonance Raman Spectra of β-Diketiminato Copper(II) Complexes
Tomoko Miyazaki, Chizu Shimokawa, Toshio Matsushita, Shinobu Itoh, Junji Teraoka*
Bull. Chem. Soc. Jpn. (Full Paper), 83 (9), 1162-1169 (2010). Selected Paper


Seven-coordinate Rhenium(III) Complexes with a Labile Coordination Site Assembled on Indium-doped Tin-oxide (ITO) Electrodes: Catalytic Reduction of Dioxygen to Hydrogen Peroxide

Hideki Sugimoto,* Hiroyuki Tano, Hiroyuki Miyake, and Shinobu Itoh*

Chem. Lett. (Communication), 39 (9), 986–988 (2010).


Oxygenation Chemistry at Mononuclear Copper(II)-Hydroquinone System with O2

Kae Tabuchi, Hideki Sugimoto, Atsushi Kunishita, Nobutaka Fujieda, and Shinobu Itoh*

Inorg. Chem. (Communication), 49 (15), 6820–6822 (2010).

Monooxo Molybdenum(VI) Complexes Possessing Olefinic Dithiolene Ligands: Probing Mo-S Covalency Contributions to Electron Transfer in DMSO Reductase Family Molybdoenzymes

Hideki Sugimoto,* Susumu Tatemoto, Koichiro Suyama, Hiroyuki Miyake, Regina P. Mtei, Shinobu Itoh,* and Martin L. Kirk*

Inorg. Chem. (Communication), 49 (12), 5368-5370 (2010).


Nickel(II) Complexes of tpa Ligands with 6-Phenyl Substituents (Phntpa).  Structure and H2O2-Reactivity

Tetsuro Tano, Yoshitaka Doi, Masayuki Inosako, Atsushi Kunishita, Minoru Kubo, Hirohito Ishimaru, Takashi Ogura, Hideki Sugimoto, and Shinobu Itoh*

Bull. Chem. Soc. Jpn. (Full Paper) 83 (5), 530-538 (2010). Selected Paper


Catalytic oxygenation of phenols by arthropod hemocyanin, an oxygen carrier protein, from Portunus trituberculatus

Nobutaka Fujieda, Aki Yakiyama, and Shinobu Itoh*

Dalton Trans. (Full Paper), 39, 3083-3092 (2010).


Hydrodesulfurization of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex Related to the Reaction Center of the Fourth Tungsten–Containing Enzyme (WOR4) from Pyrococcus furiosus.
Hideki Sugimoto,* Hiroyuki Tano, Kazuo Toyota, Reiko Tajima, Hiroyuki Miyake, Isao Takahashi, Shun Hirota, and Shinobu Itoh*
J. Am. Chem. Soc. (Communication), 132 (1), 8–9 (2010).


ブルース 有機化学概説(第2版)(化学同人,大船泰史,香月勗,西郷和彦,富岡清 監訳)
伊東 忍
教科書 (18章) (訳) (2010).

銅タンパク質の水酸化反応触媒としての応用
藤枝伸宇、伊東 忍
化学工業、61 (9), 711-715 (2010).



2009


Dioxo-Molybdenum(VI) Complexes with Ene-1,2-dithiolene Ligands: Synthesis, Spectroscopy, and Oxygen Atom Transfer Reactivity
Hideki Sugimoto,* Susumu Tatemoto, Koichiro Suyama, Hiroyuki Miyake, Shinobu Itoh,* Chao Dong, Jing Yang, and Martin L. Kirk*
Inorg. Chem. 48 (21), 10150–10157 (2009).


(μ-η2:η2-Disulfido)dinickel(II) complexes supported by 6-methyl-TPA ligands
Atsushi Kunisita, Masayuki Inosako, Minoru Kubo, Takashi Ogura, Hideki Sugimoto, and Shinobu Itoh*
Dalton Trans. (43) 9410–9417 (2009) (Selected Paper for Cover Picture).




A Stable Cu2O2 Complex Supported by an Asymmetric Dinucleating Pentapyridine Ligand Involving an Amide Linkage
Yoshimitsu Tachi, Yumi Matsukawa, Junji Teraoka, and Shinobu Itoh
Chem. Lett. 38 (3) 202–203 (2009).


Ni(II)/H2O2 Reactivity in Bis[(pyridin-2-yl)methyl]amine Tridentate Ligand Sysetm.  Aromatic Hydroxylation Reaction by Bis(μ-oxo)dinickel(III) Complex
Atsushi Kunishita, Yoshitaka Doi, Takashi Ogura, Hideki Sugimoto, and Shinobu Itoh*
Inorg. Chem. 48 (11), 4997–5004 (2009).


Mononuclear Copper(II)-Superoxo Complex that Mimics the Structure and Reactivity of the Active Centers of PHM and DβH
Atsushi Kunishita, Minoru Kubo, Hideki Sugimoto, Takashi Ogura, Kazunobu Sato, Takeji Takui,* and Shinobu Itoh*
J. Am. Chem. Soc. 131 (8), 2788–2789 (2009).


銅タンパク質による酸素の活性化
伊東 忍
生産と技術, (2009).



2008


H2O2-Reactivity of Copper(II) Complexes Supported by TPA Ligands with 6-Phenyl Substituents
Atsushi Kunishita, Minoru Kubo, Hirohito Ishimaru, Takashi Ogura, Hideki Sugimoto, and Shinobu Itoh*
Inorg. Chem. 47 (24), 12032–12039 (2008).


Reaction of β−Diketiminate Copper(II) Complexes and Na2S2
Masayuki Inosako, Atsushi Kunishita, Chizu Shimokawa, Junji Teraoka, Minoru Kubo, Takashi Ogura, Hideki Sugimoto and Shinobu Itoh*
Dalton Trans. (Article), 6250-6256 (2008).


Selenido-Bis(dithiolene) M(IV) Complexes (M = Mo and W) Potentially Related to the Nicotinic Acid Hydeosylase Reaction Center: Redox Aspects in Electrochemistry and Oxygen Atom Transfer from Me3NO to M(IV) Centers
Hiroyuki Tano, Reiko Tajima, Hiroyuki Miyake, Shinobu Itoh, and Hideki Sugimoto*
Inorg. Chem. (Communication), 47 (17), 7465–7467 (2008).


Reactions of Copper(II)–H2O2 Adducts Supported by Tridentate Bis(2-pyridylmethyl)amine Ligands: Sensitivity to Solvent and Variations in Ligand Substitution
Atsushi Kunishita, Joseph D. Scanlon, Hirohito Ishimaru, Kaoru Honda, Takashi Ogura, Masatatsu Suzuki, Christopher J. Cramer,* and Shinobu Itoh*
Inorg. Chem. (Article), 47 (18), 8222–8232 (2008).


A New Class of Sulfido/oxo(dithiolene)molybdenum(IV) Complexes Derived from Sulfido/oxo–bis(tetrasulfido)molybdenum(IV) Anions.
Hideki Sugimoto,* Koichiro Suyama, Kunihisa Sugimoto, Hiroyuki Miyake, Isao Takahashi, Shun Hirota, and Shinobu Itoh
Inorg. Chem. (Article), 47 (21), 10150–10157 (2008).


Colorimetric Response to Mercury-induced Abstraction of Triethylene Glycol Ligand from Gold Nanoparticle Surface
Tasuku Hirayama, Masayasu Taki,* Yukiyasu Kashiwagi, Masami Nakamoto, Atsushi Kunishita, Shinobu Itoh and Yukio Yamamoto
Dalton Trans, (Communication), 4705–4707 (2008).


Monooxygenase Activity of Octopus vulgaris Hemocyanin
Kenji Suzuki, Chizu Shimokawa, Chiyuki Morioka, and Shinobu Itoh*
Biochemistry (Article), 47 (27),  7108–7115 (2008).


Suggestion of an Organometallic Intermediate in an Intramolecular Dechlorination Reaction Involving Copper(I) and a ArCH2Cl Moiety
Debabrata Maiti, Amy A. Narducci Sarjeant, Shinobu Itoh and Kenneth D. Karlin*
J. Am. Chem. Soc. (Communication), 130 (17), 5644-5645 (2008).


Reactivity of Mononuclear Alkylperoxo Copper(II) Complex. O–O Bond Cleavage and C–H Bond Activation
Atsushi Kunishita, Hirohito Ishimaru, Satoru Nakashima, Takashi Ogura, and Shinobu Itoh*
J. Am. Chem. Soc. (Communication), 130 (13), 4244–4245 (2008).