2024
Copper Complexes with Protein‐Based N‐Donor Ligands as cis‐Selective Nascent Cyclopropanases
Nobutaka Fujieda, Atsuki Matsuo, Shinobu Itoh
Chem. Eur. J., 2024, e202402803 (1 of 5).
DOI: 10.1002/chem.202402803
Structure and substitution effects of iron complexes of dibenzotetraaza[14]annulene on oxygen reduction catalysis
Masafumi Asahi, Shin-ichi Yamazaki, Shinobu Itoh, Tsutomu Ioroi
Inorg. Chim. Acta., 2024, 572, 12991.
DOI: 10.1016/j.ica.2024.122291
Oxidation mechanism of phenols by copper(II)-halide complexes
Lan Yang, Rin Ito, Hideki Sugimoto, Yuma Morimoto, Shinobu Itoh
Chem Commum., 2024, 60, 7589-7589
DOI: 10.1039/d4cc02483d
Selective Alkane Hydroxylation in a Fluorous Solvent System Catalyzed by a Fluorocarbon-Soluble Transition-Metal Catalyst
Yuma Morimoto, Yuki Shimaoka, Kosuke Fukui, Shinobu Itoh
ACS Omega., 2024, 9, 22, 23624-23633.
DOI: 10.1021/acsomega.4c01204
A rhodium(II)/rhoium(III) redox couple for C-H bond amination with alkylazides: a rhodium(III)-nitrenoid intermediate with a tetradentate [14]-macrocyclic ligand
Hideki Sugimoto, Megumu Sakaida, Yoshihito Shiota, Mayuko Miyanishi, Yuma Morimoto, Kazunari Yoshizawa, Shinobu Itoh
Dalton Trans., 2024, 53, 1607-1615.
DOI: 10.1039/d3dt03429a
Asymmetric Michael addition catalysed by copper–amyloid complexes
Nobutaka Fujieda, Atsushi Tonomura, Tomofumi Mochizuki, Shinobu Itoh
RSC Adv., 2024, 14, 206-210.
DOI: 10.1039/d3ra07900g
2023
Mechanistic Studies on Oxygen-Insertion into Osmium(III)–Carbon Bond via High-Valent Oxido-Osmium(V) Complex
Hideki Sugimoto, Kurumi Aoki, Shinobu Itoh
Bull. Chem. Soc. Jpn., 2023, 96 (11), 1310-1315.
DOI: 10.1246/bcsj.20230213
Mechanistic studies on catalytic alkane oxidation by Murahashi’s O2/copper(ii)/aldehyde system
Kohei Yamaguchi, Yuya Uemura, Hideki Sugimoto, Rin Ito, Yuma Morimoto, Shinobu Itoh
Catal. Sci. Technol., 2023, 13, 5859-5867.
DOI: 10.1039/d3cy00944k
Characterization and Reactivity Studies of Mononuclear Tetrahedral Copper(II)–Halide Complexes
Yang Lan, Yuma Morimoto, Ikuma Shimizu, Hideki Sugimoto, Shinobu Itoh
Inorg. Chem., 2023, 62, 27, 10539–10547.
DOI: 10.1021/acs.inorgchem.3c00320
Oxygenase mimicking immobilised iron complex catalysts for alkane hydroxylation with H2O2
Seiya Sakakura, Ryunosuke Kitamoto, Kazuki Goto, Seito Miura, Takamasa Takeda, Masaya Okamura, Arisa Fukatsu, Shinobu Itoh, Shiro Hikichi
Catal. Sci. Technol., 2023, 13, 4839-4846.
DOI: 10.1039/D3CY00698K
2022
Alkane hydroxylation by m-chloroperbenzoic acid catalyzed by nickel(II) complexes of linear N4-tetradentate ligands
Takuma Wada, Hideki Sugimoto, Yuma Morimoto, Shinobu Itoh
Polyhedron. 2022, 227, 116150-116150.
DOI: 10.1016/j.poly.2022.116150
Dioxygen Activation and Mandelate Decarboxylation by Iron(II) Complexes of N4 Ligands: Evidence for Dioxygen-Derived Intermediates from Cobalt Analogues
Rahul Dev Jana, Biswarup Chakraborty, Sayantan Paria, Takehiro Ohta, Reena Singh, Sourav Mandal, Satadal Paul, Shinobu Itoh, Tapan Kanti Paine
Inorg. Chem. 2022, 61 (27), 10461-10476.
DOI: 10.1021/acs.inorgchem.2c01308
Alkane Oxidation with H2O2 Catalyzed by OsO4-carboxylate Adduct and Its Application to Heterogeneous Catalyst
Tomohiro Fujimoto, Yuta Ueda, Hideki Sugimoto, Jun Nakazawa, Shiro Hikichi, Shinobu Itoh
Chem. Lett. 2024, 51 (3), 231-234.
DOI: 10.1246/cl.210751
Halide-Adducts of OsO4. Structure and Reactivity in Alcohol-Oxidation
Tomohiro Fujimoto, Yuka Hirata, Hideki Sugimoto,* Mayuko Miyanishi, Yoshihito Shiota, Kazunari Yoshizawa,* and Shinobu Itoh*
Bull. Chem. Soc. Jpn., 2022, 95 (1), 64-72. Selected Paper
DOI: 10.1246/bcsj.20210377
C(sp3)–H bond activation by carboxylate-adduct of osmium tetroxide (OsO4)
Tomohiro Fujimoto, Yuka Hirata, Hideki Sugimoto,* Mayuko Miyanishi, Yoshihito Shiota, Kazunari Yoshizawa* and Shinobu Itoh*
Dalton Trans. 2022, 51 (3), 1123-1130.
DOI: 10.1039/D1DT03819B
2021
Tin(II)-Nitrene Radical Complexes Formed by Electron Transfer from Redox-Active Ligand to Organic Azides and Their Reactivity in C(sp3)–H Activation
Hideki Sugimoto,* Mayuka Yano, Kazunobu Sato,* Mayuko Miyanishi, Kenji Sugisaki, Yoshihito Shiota, Akira Kaga, Kazunari Yoshizawa,* and Shinobu Itoh*
Inorg. Chem. 2021, 60 (24), 18603-18607. Inside Cover
DOI: doi.org/10.1021/acs.inorgchem.1c02806
Revisiting Alkane Hydroxylation with m-CPBA (m-Chloroperbenzoic Acid) Catalyzed by Nickel(II) Complexes
Tomoya Shinke, Mayu Itoh, Sachiko Yanagisawa, Yuma Morimoto, Hideki Sugimoto, Minoru Kubo, and Shinobu Itoh*
Chem. Eur. J. 2021, 27 (59), 14730-14737.
DOI: 10.1002/chem.202102532
Controlling Reactivity of Copper(II) Acylperoxide Complexes
Yuma Morimoto, Makito Kawai, Aya Nakanishi, Hideki Sugimoto, and Shinobu Itoh*
Inorg. Chem. 2021, 60, 8554-8565. Inside Cover
DOI: 10.1021/acs.inorgchem.1c00475
Oxygen Atom Insertion into Osmium–Carbon Bond via Organometallic Oxido-Osmium(V) Intermediate
Hideki Sugimoto,* Kurumi Aoki, Mayuko Miyanishi, Yoshihito Shiota, Kazunari Yoshizawa, Kazunari, and Shinobu Itoh*
Organometallics, 2021, 40 (2), 102-106
DOI: 10.1021/acs.organomet.0c00772
Hydroxylation of Unactivated C(sp3)–H Bonds with m-CPBA Catalyzed by FeIII-complex Supported by Trianionic Planar Tetradentate Ligand
Yuma Morimoto,* Shinichi Hanada, Ryusuke Kamada, Arisa Fukatsu, Shinsuke Okabe, Hideki Sugimoto, and Shinobu Itoh*
Inorg. Chem. 2021, 60 (11), 7641-7649. Front Cover
DOI: 10.1021/acs.inorgchem.0c03469
Review in Japanese
チロシナーゼ反応機構における銅活性酸素種の動的挙動
藤枝伸宇、伊東 忍
生化学, 2021, 93 (4), 521-525.
Journal of Japanese Biochemical Society 93(4): 521-525 (2021)
DOI: 10.14952/SEIKAGAKU.2021.930521
Book Chapter
8.10 – Dioxygen-Binding in Metalloproteins and Corresponding Models
Shinobu Itoh, Hiroshi Fujii
in Constable, E.; Parkin, G.; Que, L., Jr. (Ed.), Comprehensive Coordination Chemistry III (pp. 200-237). Elsevier Science: 2021.
2020
Modelling a ‘histidine brace’ motif in mononuclear copper monooxygenases
Arisa Fukatsu; Yuma Morimoto; Hideki Sugimoto; Shinobu Itoh*
Chem. Commun. 2020, 56, 5123-5126.
DOI: 10.1039/D0CC01392G
Chosen as an inside cover
2019
Direct Observation of Primary C–H Bond Oxidation by an Oxido-Iron(IV) Porphyrin π-Radical Cation Complex in a Fluorinated Carbon Solvent
Yuma Morimoto*; Yuki Shimaoka; Yuri Ishimizu; Hiroshi Fujii*; Shinobu Itoh*
Angew. Chem. Int. Ed. 2019, 58, 10863-10866.
DOI: 10.1002/anie.201901608
Characterization and Reactivity of a Tetrahedral Copper(II)-Alkylperoxido Complex
Ikuma Shimizu; Yuma Morimoto; Gunasekaran Velmurugan; Tulika Gupta; Sayantan Paria; Takehiro Ohta; Hideki Sugimoto; Takashi Ogura; Peter Comba*; Shinobu Itoh*
Chem.–Eur. J. 2019, 25, 11157-11165
DOI: 10.1002/chem.201902669
Oxido-Hydroxido- and Oxido-Aminato-Osmium(V) Complexes with a Cyclohexanediamine-Based Tetradentate Ligand as Active Oxidants for Dihydroxylation and Aminohydroxylation of Alkenes
Tomohiro Fujimoto; Hideki Sugimoto*; Kenichiro Kai; Kazuki Maeda; Shinobu Itoh*
Eur. J. Inorg. Chem. 2019, 2891-2898.
DOI: 10.1002/ejic.2019003390
Oxido-alcoholato/thiolato-molybdenum(VI) complexes with a dithiolene ligand generated by oxygen atom transfer to the molybdenum(IV) complexes.
Hideki Sugimoto;* Masanori Sato; Kaoru Asano; Takeyuki Suzuki; Takashi Ogura; Shinobu Itoh*
Inorg. Chim. Acta, 2019, 485, 42-48.
DOI: 10.1016/j.ica.2018.10.001
Cupric-superoxide complex that induces a catalytic aldol reaction-type C–C bond formation
Tsukasa Abe; Yuta Hori; Yoshihito Shiota; Takehiro Ohta; Yuma Morimoto; Hideki Sugimoto; Takashi Ogura; Kazunari Yoshizawa*; Shinobu Itoh*
Commun. Chem. 2019, 2, Article number: 12
(DOI: 10.1038/s42004-019-0115-6)
Our first paper in 2019 is published from Communication of Chemistry, which is a new chemistry journal of Nature.com.
2018
Non-innocent Ligand in Rhodium(III) Complex Catalyzed C-H Bond Amination with Tosyl Azide
Daiki Fujita, Hideki Sugimoto*, Yuma Morimoto, Shinobu Itoh*
Inorg. Chem. 2018, 57, 9738–9747.
(DOI: 10.1021/acs.inorgchem.8b00289)
A Bis(µ-oxido)dinickel(III) Complex with a Triplet Ground State
Yuma Morimoto*, Yusaku Takagi, Toru Saito, Takehiro Ohta, Takashi Ogura, Norimitsu Tohnai, Motohiro Nakano, Shinobu Itoh*
Angew. Chem., Int. Ed. 2018, 57, 7640-7643.
(DOI: 10.1002/anie.201802779)
Copper(I)–Dioxygen Reactivity in the Isolated Cavity of a Nanoscale Molecular Architecture
Sayantan Paria, Yuma Morimoto, Takehiro Ohta, Shinsuke Okabe, Hideki Sugimoto, Takashi Ogura, Shinobu Itoh*
Eur. J. Inorg. Chem. 2018, 1976-1983. (DOI: 10.1002/ejic.201800029)
Tyrosinases in Organic Chemistry: A Versatile Tool for the α-Arylation of -Dicarbonyl Compounds
Roxanne Krug, Dennis Schröder, Jan Gebauer, Sanel Suljić, Yuma Morimoto, Nobutaka Fujieda, Shinobu Itoh, and Jörg Pietruszka*
Eur. J. Org. Chem. 2018, 1789–1796.
(DOI: 10.1002/ejoc.201800188)
Osmium Complexes Coordinated with Poly(pyridylmethyl)diamine Hexadantate Ligands
Hideki Sugimoto,* Kahori Kiriyama, and Shinobu Itoh*
Eur J. Inorg. Chem. 2018 (2), 178-185.
DOI: 10.1002/ejic.201701173
Crystal Structure and Oxygen Reduction Reaction (ORR) Activity of Copper(II) Complexes of Pyridylmethylamine Ligands Containing a Carboxy Group
Masafumi Asahi,* Shin-ichi Yamazaki, Yuma Morimoto, Shinobu Itoh, Tsutomu Ioroi
Inorg. Chim. Acta, 2018, 471, 91-98.
DOI: https://doi.org/10.1016/j.ica.2017.10.031.
2-(2-Pyridyl)ethylamine (Pye) ligands in copper(I)-dioxygen chemistry
Shinobu Itoh,* Tsukasa Abe, Yuma Morimoto, and Hideki Sugimoto
Inorg. Chim. Acta (Special issue of “Bio-inorganic and bio-inspired chemistry of copper”), 2018, 481, 38-46.
DOI: 10.1016/j.ica.2017.09.017
生体模倣型オスミウム錯体を触媒とするアルケンの酸化的変換反応
杉本秀樹 ・ 伊東 忍
有機合成化学協会誌（総合論文）, 75 (9), 929-940 (2017). DOI: 10.5059/yukigoseikyokaishi.75.929
銅含有モノオキシゲナーゼによる酸素分子の活性化機構
伊東 忍、藤枝伸宇
生化学、90 (3), 320-327 (2018)
DOI: 10.14952/SEIKAGAKU.2018.900320
Structures, Functions, and Assembly of Tyrosinases and Hemocyanins
Nobutaka Fujieda and Shinobu Itoh
Encyclopedia of Inorganic and Bioinorganic Chemistry (ISBN 9781119159834),
edited by Robert A. Scott., John Wiley & Sons, Ltd: Chichester, UK, 2017.
DOI: 10.1002/9781119951438.eibc2474 (SEPTEMBER 22, 2017).
2017
Copper-Catalyzed Selective Oxygenation of Methyl and Benzyl Substituents in Pyridine with O2
Tsukasa Abe, Shinji Tanaka, Atsuko Ogawa, Masanori Tamura, Kazuhiko Sato,* and Shinobu Itoh*
Chem. Lett. 2017, 47 (3), 348-350.
DOI: http://dx.doi.org/10.1246/cl.161074. Publication Date (Web): March 29, 2017.
Dioxygenation of Flavonol Catalyzed by CuII-complexes Supported by Carboxylate-containing Ligands. Structural and Functional Models of Quercetin 2,4-Dioxygenase (2,4-QD)
Ying-Ji Sun,* Pei Li, Qian-Qian Huang, Jian-Jun Zhang, and Shinobu Itoh*
Eur. J. Inorg. Chem. 2017 (13), 1845-1854.
DOI: 10.1002/ejic.201601371. Publication Date (Web): February 16, 2017.
A Well-Defined Osmium-Cupin Complex: Hyperstable Artificial Osmium Peroxygenase
Nobutaka Fujieda,* Takumi Nakano, Yuki Taniguchi, Haruna Ichihashi, Hideki Sugimoto, Yuma Morimoto, Yousuke Nishikawa, Genji Kurisu, and Shinobu Itoh*
J. Am. Chem. Soc. 2017, 139 (14), 5149-5155.
DOI: 10.1021/jacs.7b00675. Publication Date (Web): March 24, 2017.
Generation and characterisation of a stable nickel(II)-aminoxyl radical complex
Arnaud Parrot, Yuma Morimoto, Sayantan Paria, Hideki Sugimoto, Nobutaka Fujieda and Shinobu Itoh*
Dalton Trans. 2017, 46 (25), 8013-8016.
DOI: 10.1039/C7DT01789H. Publication Date (Web): June 16, 2017.
Catalytic C–H amination driven by intramolecular ligand-to-nitrene one-electron transfer through a rhodium(III) center
Daiki Fujita, Hideki Sugimoto,* Yoshihito Shiota, Yuma Morimoto, Kazunari Yoshizawa and Shinobu Itoh*
Chem. Comm. 2017, 53 (35), 4849-4852.
DOI: 10.1039/C7CC01840A, Publication Date (Web): April 19, 2017.
Geometric Effects on O–O Bond Scission of Copper(II)-alkylperoxide Complexes
Tsukasa Abe, Yuma Morimoto, Kaoru Mieda, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, and Shinobu Itoh*
J. Inorg. Biochem. 2017, 177, 375-383.
DOI: 10.1016/j.jinorgbio.2017.08.016, Publication Date (Web): September 9, 2017.
Tetrahedral Copper(II) Complexes with a Labile Coordination Site Supported by a tris-Tetramethylguanidinato Ligand
Ikuma Shimizu, Yuma Morimoto, Dieter Faltermeier, Marion Kerscher, Sayantan Paria, Tsukasa Abe, Hideki Sugimoto, Nobutaka Fujieda, Kaori Asano, Takeyuki Suzuki, Peter Comba,* and Shinobu Itoh*
Inorg. Chem. 2017, 2017, 56 (16), 9634-9645.
DOI: 10.1021/acs.inorgchem.7b01154. Publication Date (Web): July 28, 2017.
生体模倣型オスミウム錯体を触媒とするアルケンの酸化的変換反応
杉本秀樹 ・ 伊東 忍
有機合成化学協会誌（総合論文）, 75 (9), 929-940 (2017).
2-(2-Pyridyl)ethylamine (Pye) ligands in copper(I)-dioxygen chemistry
Shinobu Itoh,* Tsukasa Abe, Yuma Morimoto, and Hideki Sugimoto
Inorg. Chim. Acta (Special issue of “Bio-inorganic and bio-inspired chemistry of copper”), 2017, in press.
DOI: 10.1016/j.ica.2017.09.017,
続 実験を安全に行うために−基本操作･基本測定 編−（第４版）
西脇永敏・伊東 忍・小廣和哉・南方聖司
化学同人、2017年2月10日
ISBN 978-4-7598-1834-5
Structures, Functions, and Assembly of Tyrosinases and Hemocyanins
Nobutaka Fujieda and Shinobu Itoh
Encyclopedia of Inorganic and Bioinorganic Chemistry (ISBN 9781119159834),
edited by Robert A. Scott., John Wiley & Sons, Ltd: Chichester, UK, 2017.
DOI: 10.1002/9781119951438.eibc2474 (SEPTEMBER 22, 2017).
2016
Acid-base and redox equilibria of a tris(2-pyridylmethyl)amine copper complex; their effects on electrocatalytic oxygen reduction by the complex.
Masafumi Asahi, Shin-ichi Yamazaki, Shinobu Itoh, Tsutomu Ioroi
Electrochimica Acta, in press (2016).
Oxidative Cyclization of 1,5-Dienes with Hydrogen Peroxide Catalyzed by an Osmium(III) Complex: Synthesis of cis- Tetrahydrofurans
Hideki Sugimoto, Takayuki Kanetake, Kazuki Maeda, and Shinobu Itoh
Org. Lett. 18 (6), 1246–1249 (2016).
Cerium-Complex-Catalyzed Oxidation of Arylmethanols under Atmospheric Pressure of Dioxygen and Its Mechanism through a Side-On μ-Peroxo Dicerium(IV) Complex.
Mitali Paul, Satoru Shirase, Yuma Morimoto, Laurent Mathey, Balasubramanian Murugesapandian, Shinji Tanaka, Shinobu Itoh, Hayato Tsurugi,* and Kazushi Mashima*
Chem. Eur. J. 22 (12), 4008 – 4014 (2016).
A Model for the Active-Site Formation Process in DMSO Reductase Family Molybdenum Enzymes Involving Oxido−Alcoholato and Oxido−Thiolato Molybdenum(VI) Core Structures
Hideki Sugimoto,* Masanori Sato, Kaori Asano, Takeyuki Suzuki, Kaoru Mieda, Takashi Ogura, Takashi Matsumoto, Logan J. Giles, Amrit Pokhrel, Martin L. Kirk,* and Shinobu Itoh*
Inorg. Chem. 55 (4), 1542-1550 (2016).
Controlling Dicopper Protein Functions
Nobutaka Fujieda and Shinobu Itoh*
Bull. Chem. Soc. Jpn. 2016, 89 (7), 733-742 (2016)
Award Accounts (CSJ Award for Creative Work in 2014).
DOI: 10.1246/bcsj.20150444
フロンティア生物無機化学 錯体化学会フロンティア選書
伊東 忍、青野重利、林 高史 編著
三共出版、2016年12月1日
ISBN: 978-4-7827-0756-2
2015
Generation, Characterization, and Reactivity of a CuII−Alkylperoxide/Anilino Radical Complex: Insight into the O−O Bond Cleavage Mechanism
Sayantan Paria, Takehiro Ohta, Yuma Morimoto, Takashi Ogura, Hideki Sugimoto, Nobutaka Fujieda, Kei Goto, Kaori Asano, Takeyuki Suzuki, and Shinobu Itoh*
J. Am. Chem. Soc. 137 (34), 10870–10873 (2015).
cis-1,2-Aminohydroxylation of Alkenes Involving a Catalytic Cycle of Osmium(III) and Osmium(V) Centers: OsV(O)(NHTs) Active Oxidant with a Macrocyclic Tetradentate Ligand
Hideki Sugimoto,* Akine Mikami, Kenichiro Kai, P. K. Sajith, Yoshihito Shiota, Kazunari Yoshizawa,* Kaori Asano, Takeyuki Suzuki, and Shinobu Itoh*
Inorg. Chem. 54 (14), 7073-7082 (2015). 10.1021/acs.inorgchem.5b01083 (June 30, 2015).
Developing Mononuclear Copper Active-oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions
Shinobu Itoh
Acc. Chem. Res. 48 (7), 2066-2074 (2015). 10.1021/acs.accounts.5b00140 (June 18, 2015).
Direct Hydroxylation of Benzene to Phenol Using Hydrogen Peroxide Catalyzed by Nickel Complexes Supported by Pyridylalkylamine Ligands
Yuma Morimoto, Shuji Bunno, Nobutaka Fujieda, Hideki Sugimoto, and Shinobu Itoh*
J. Am. Chem. Soc. 137 (18), 5867-5870 (2015). 10.1021/jacs.5b01814 (May 4, 2015).
Solubilisation of a 2,2-diphenyl-1-picrylhydrazyl radical in water by β-cyclodextrin to evaluate the radical-scavenging activity of antioxidants in aqueous media
Ikuo Nakanishi, Kei Ohkubo, Kohei Imai, Masato Kamibayashi, Yasuo Yoshihashi, Ken-ichiro Matsumoto, Kiyoshi Fukuhara, Katsuhide Terada, Shinobu Itoh, Toshihiko Ozawa and Shunichi Fukuzumi
Chem. Commun. 51, 8311-8314 (2015). 10.1039/C5CC02236C (April 4, 2015)
Fungal Pro-tyrosinase
Nobutaka Fujieda and Shinobu Itoh
Handbook of Metalloproteins to the Encyclopedia of Inorganic and Bioinorganic Chemistry
Robert Huber, Thomas Poulos, and Karl Wieghardt, Eds, John Wiley & Sons, UK, 2015, in press.
β-Diketiminates as Redox Non-innocent Supporting Ligands in Coordination Chemistry
Shinobu Itoh and Yuma Morimoto
Chemical Science of π-Electron Systems, Akasaka, T.; Osuka, A.; Fukuzumi, S.; Kandori, H.; Aso, Y. Eds., Springer, Tokyo, 2015, pp 715-730.
Redox behavior of novel nickel and palladium complexes supported by trianionic non-innocent ligand containing β-diketiminate and phenol groups
Yuma Morimoto, June Takaichi, Shinichi Hanada, Kei Ohkubo, Hideki Sugimoto, Nobutaka Fujieda, Shunichi Fukuzumi and Shinobu Itoh*
J. Porphyrins Phthalocyanines 19, 377–387 (2015). 10.1142/S1088424615500248
鉄と酸素が出会った瞬間を捉える〜ようやく姿を現したスーペルオキシド鉄錯体
森本祐麻･伊東 忍
月刊「化学」（最新のトピックス）, 70 (9), 64–65 (2015).
ブルース有機化学（第7版）
Paula Y. Bruice著、大船泰史ら（監修）
伊東 忍ら（訳）
化学同人、pp 1235-1313（第23，24章）（2015）
2014
A Tetradentate β-Diiminato Ligand Containing Phenolate Substituents: Flexivalent Coordination to Mn(III), Co(III), Ni(II), and Cu(II)
Fadhil Lafta Faraj, Hamid Khaledi,* Yuma Morimoto, Shinobu Itoh, Marilyn M. Olmstead, and Hapipah Mohd Ali
Eur. J. Inorg. Chem. 2014, 5752-5759.
Geometric Control of Nuclearity in Copper(I)/Dioxygen Chemistry
Tsukasa Abe, Yuma Morimoto, Tetsuro Tano, Kaoru Mieda, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, and Shinobu Itoh*
Inorg. Chem. 53 (16), 8786-8794 (2014). 10.1021/ic501461n
Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer solution: relationship between activity and redox potential
Masafumi Asahi,* Shin-ichi Yamazaki, Shinobu Itoh, and Tsutomu Ioroi
Dalton Trans. 43 (28), 10705-10709 (2014). 10.1039/C4DT00606B
Redox Chemistry of Nickel(II)-Complexes Supported by a Series of Non-innocent β-Diketiminate Ligands
June Takaichi, Yuma Morimoto, Kei Ohkubo, Chizu Shimokawa, Takayuki Hojo, Seiji Mori,* Haruyasu Asahara, Hideki Sugimoto, Nobutaka Fujieda, Nagatoshi Nishiwaki, Shunichi Fukuzumi, and Shinobu Itoh*
Inorg. Chem. 53 (12), 6159-6169 (2014). 10.1021/ic5006693
Copper complexes supported by an N2S-tridentate ligand as active site models of copper monooxygenases
Tetsuro Tano, Hideki Sugimoto and Shinobu Itoh*
Dalton Trans. 43 (12), 4871-4877 (2014). 10.1039/C3DT52952E
2013
Redox Properties of Mononuclear Copper(II)-Superoxide Complex
Tetsuro Tano, Yuri Okubo, Atsushi Kunishita, Minoru Kubo, Hideki Sugimoto, Nobutaka Fujieda, Takashi Ogura, and Shinobu Itoh*
Inorg. Chem. 52 (18), 10431-10437 (2013).
Flavonolate Complexes of MII (M = Mn, Fe, Co, Ni, Cu, and Zn). Structural and Functional Models for the ES (Enzyme-Substrate) Complex of Quercetin 2,3-Dioxygenase
Ying-Ji Sun,* Qian-Qian Huang, Tetsuro Tano, and Shinobu Itoh
Inorg. Chem. 52 (19), 10936-10948 (2013).
Oxo-carboxylato-molybdenum(VI) complexes possessing dithiolene ligand related to the active site of type II class of DMSOR family of molybdoenzymes
Hideki Sugimoto,* Masanori Sato, Logan J. Giles, Kaori Asano, Takeyuki Suzuki, Martin L. Kirk,* and Shinobu Itoh*
Dalton Trans. in press (2013).
Crystal Structures Of Copper-Depleted And Copper-Bound Fungal Pro-Tyrosinase: Insights Into Endogenous Cysteine-Dependent Copper Incorporation
Nobutaka Fujieda, Shintaro Yabuta, Takuya Ikeda, Takuji Oyama, Norifumi Muraki, Genji Kurisu,* and Shinobu Itoh*
J. Biol. Chem. 288 (30), 22128-22140 (2013).
Osmium(III) and Osmium(V) Complexes Bearing a Macrocyclic Ligand: A Simple and Efficient Catalytic System for cis-Dihydroxylation of Alkenes with Hydrogen Peroxide
Hideki Sugimoto,* Kenji Ashikari, and Shinobu Itoh*
Chem. Asian J. 8 (9), 2154-2160 (2013).
C–H Bond Activation of the Methyl Group of Supporting Ligand in an Osmium(III) Complex upon the Reaction with H2O2: Formation of an Organometallic Osmium(IV) Complex
Hideki Sugimoto,* Kenji Ashikari, and Shinobu Itoh*
Inorg. Chem. 52 (2), 543-545 (2013).
Copper complexes of non-innocent β-diketiminate ligand containing phenol groups
June Takaichi, Kei Ohkubo, Hideki Sugimoto, Motohiro Nakano, Daisuke Usa, Hiroaki Maekawa, Nobutaka Fujieda, Nagatoshi Nishiwaki, Shu Seki, Shunichi Fukuzumi, and Shinobu Itoh*
Dalton Trans. 41 (7), 2438-2444 (2013).
A new series of bis(ene-1,2-dithiolato)tungsten(IV), -(V), -(VI) complexes as reaction centre models of tungsten enzymes: preparation, crystal structures and spectroscopic properties.
Hideki Sugimoto,* Kohei Hatakeda, Kazuo Toyota, Susumu Tatemoto, Minorun Kubo, Takashi Ogura and Shinobu Itoh*
Dalton Trans. 41 (9), 3059-3070 (2013).
Oxo-sulfido- and oxo-selenido-molybdenum(VI) complexes possessing dithiolene ligand related to the active sites of hydroxylases of molybdoenzymes: Low temperature preparation and characterisation
Hideki Sugimoto,* Susumu Tatemoto, Kazuo Toyota, Minoru Kubo, and Shinobu Itoh*
Chem. Commun. 49 (39), 4358-4360 (2013).
Activation Mechanism of MelB Tyrosinase from Aspergillus oryzae by Acidic Treatment
Nobutaka Fujieda,* Michiaki Murata, Shintaro Yabuta, Takuya Ikeda, Chizu Shimokawa, Yukihiro Nakamura, Yoji Hata, Shinobu Itoh*
J. Biol. Inorg. Chem. 18 (1), 19-26 (2013).